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SchemaSpy analyzes database metadata to reverse engineer dynamic Entity Relationship (ER) diagrams. It works with just about any JDBC-compliant database (Oracle/MySQL/DB2/SQL Server/PostgreSQL/Sybase/etc.) and can identify Ruby on Rails as well as other implied relationships.
Dabo is a 3-tier, cross-platform desktop application development framework, written in Python atop the wxPython GUI toolkit. And while Dabo is designed to create database-centric apps, that is not a requirement. Lots of people are using Dabo for the GUI tools to create apps that have no need to connect to a database at all.